苄基季铵盐在氨基碱金属化合物的作用下得到铵叶立德中间体，接着进行[2,3]-Wittig重排生成邻甲基苄胺的反应。
反应机理
反应实例
参考文献
1. (a) Sommelet, M. Compt. Rend. 1937, 205, 56–58. (b) Kantor, S. W.; Hauser, C. R. J. Am. Chem. Soc. 1951, 73, 4122–4131. Charles R. Hauser (1900–1970) was a professor at Duke University.
2. Shirai, N.; Sato, Y. J. Org. Chem. 1988, 53, 194–196.
3. Shirai, N.; Watanabe, Y.; Sato, Y. J. Org. Chem. 1990, 55, 2767–2770.
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5. Klunder, J. M. J. Heterocycl. Chem. 1995, 32, 1687–1691.
6. Maeda, Y.; Sato, Y. J. Org. Chem. 1996, 61, 5188–5190.
7. Endo, Y.; Uchida, T.; Shudo, K. Tetrahedron Lett. 1997, 38, 2113–2116.
8. Hanessian, S.; Talbot, C.; Saravanan, P. Synthesis 2006, 723–734.
9. Liao, M.; Peng, L.; Wang, J. Org. Lett. 2008, 10, 693–696.
10. Tayama, E.; Orihara, K.; Kimura, H. Org. Biomol. Chem. 2008, 6, 3673–3680.
11. Zografos, A. L. In Name Reactions in Heterocyclic Chemistry-II, Li, J. J., Ed.; Wiley: Hoboken, NJ, 2011, pp 197–206. (Review).
12. Tayama, Eiji; Sato, Ryota; Takedachi, Keisuke; Iwamoto, Hajime; Hasegawa, Eietsu Tetrahedron 2012, 68, 4710–4718.
编译自：Name Reactions （A Collection of Detailed Reaction Mechanisms）, Jie Jack Li, Sommelet–Hauser rearrangement，page 570-571.
相关反应介绍
[2,3]-Wittig重排
碱处理烯丙基醚重排得到高烯丙醇的反应，也被称为Still-Wittig重排。反应机理同Sommelet-Hauser重排类似。
反应机理
反应实例
参考文献
1. Cast, J.; Stevens, T. S.; Holmes, J. J. Chem. Soc. 1960, 3521-
